MICROWAVE-ASSISTED GREEN SYNTHESIS OF CARBON DOTS DERIVED FROM MELON PEEL WASTE AS AN ECO-FRIENDLY FLUORESCENT SENSOR FOR Fe³⁺ CONTAMINATION
DOI:
10.29303/ipr.v9i3.594Downloads
Abstract
This research successfully demonstrates the valorization of melon peel waste into fluorescent carbon dots (CDs) using a straightforward microwave-assisted synthesis method. The synthesized CDs were comprehensively characterized, revealing optimal optical properties for sensing applications. Ultraviolet-visible spectroscopy revealed characteristic absorption peaks at 260 nm and 305 nm, corresponding to the carbon core and surface functional groups, respectively. Furthermore, photoluminescence spectroscopy under 245 nm excitation showed a strong blue emission peak at 453 nm. The practical utility of these nanoparticles was confirmed through their application as a fluorescent sensor for Fe³⁺ ions. The interaction resulted in significant fluorescence quenching and a distinct blue shift of the emission peak to 448 nm, indicating high sensitivity and a strong quenching response, leading to a ~67% decrease in emission intensity. These findings confirm that melon peel-derived CDs are a promising, eco-friendly material for developing effective probes for detecting heavy metals in environmental monitoring.Keywords:
Carbon Dots Melon Peel Waste Heavy Metal Sensing Fe³⁺ Detection UV-Vis SpectroscopyReferences
[1] R. F. Septiyanto, Q. Qothrunnada, A. Saefullah, and I. Affifah, “Synthesis of C-Dots Based on Bitter Melon Peel using the Bottom-UP Method,” Computational and Experimental Research in Materials and Renewable Energy, vol. 7, no. 1, p. 1, May 2024.
[2] S. Kurnia, R. F. Septiyanto, Y. R. D. M, and I. Affifah, “Pengaruh Carbon Dots Dari Kulit Kentang Dengan Teknik Iradiasi Gelombang Mikro Terhadap Pertumbuhan Tanaman Cabai,” Jurnal Pendidikan Fisika dan Sains (JPFS), vol. 8, no. 1, pp. 19–28, Mar. 2025.
[3] C. Wang, K. Jiang, Z. Xu, H. Lin, and C. Zhang, “Glutathione modified carbon-dots: from aggregation-induced emission enhancement properties to a ‘turn-on’ sensing of temperature/Fe 3+ ions in cells,” Inorg. Chem. Front., vol. 3, no. 4, pp. 514–522, 2016.
[4] M. P. Aji et al., “Carbon dots from dragonfruit peels as growth-enhancer on ipomoea aquatica vegetable cultivation,” Advances in Natural Sciences: Nanoscience and Nanotechnology, vol. 11, no. 3, p. 035005, Jun. 2020.
[5] X.-Y. Jiao, L. Li, S. Qin, Y. Zhang, K. Huang, and L. Xu, “The synthesis of fluorescent carbon dots from mango peel and their multiple applications,” Colloids Surf. A Physicochem. Eng. Asp., vol. 577, pp. 306–314, Sep. 2019.
[6] F. A. R. Putri and C. Asnadi, “Pemisahan Ion Besi dalam Larutan dengan Teknik Adsorpsi Menggunakan Karbon Aktif,” WARTA AKAB, vol. 45, no. 2, Dec. 2021.
[7] W. A. Qureshi, B. Vivekanandan, J. A. Jayaprasath, D. Ali, S. Alarifi, and K. Deshmukh, “Antimicrobial Activity and Characterization of Pomegranate Peel-Based Carbon Dots,” J. Nanomater., vol. 2021, pp. 1–6, Nov. 2021.
[8] M. Wang et al., “Sensitivity fluorescent switching sensor for Cr (VI) and ascorbic acid detection based on orange peels-derived carbon dots modified with EDTA,” Food Chem., vol. 318, p. 126506, Jul. 2020.
[9] T. Watcharamongkol, P. Khaopueak, C. Seesuea, and K. Wechakorn, “Green hydrothermal synthesis of multifunctional carbon dots from cassava pulps for metal sensing, antioxidant, and mercury detoxification in plants,” Carbon Resources Conversion, vol. 7, no. 2, p. 100206, Jun. 2024.
[10] C. Zhao, X. Li, C. Cheng, and Y. Yang, “Green and microwave-assisted synthesis of carbon dots and application for visual detection of cobalt (II) ions and pH sensing,” Microchemical Journal, vol. 147, pp. 183–190, Jun. 2019.
[11] T. Yu, H. Wang, C. Guo, Y. Zhai, J. Yang, and J. Yuan, “A rapid microwave synthesis of green-emissive carbon dots with solid-state fluorescence and pH-sensitive properties,” R. Soc. Open Sci., vol. 5, no. 7, Jul. 2018.
[12] O. Soledad-Flores, S. J. Bailón-Ruiz, and F. Román-Velázquez, “Rapid Synthesis of Non-Toxic, Water-Stable Carbon Dots Using Microwave Irradiation,” Micro, vol. 4, no. 4, pp. 659–669, Nov. 2024.
[13] P. Siahcheshm and P. Heiden, “High quantum yield carbon quantum dots as selective fluorescent turn-off probes for dual detection of Fe2+/Fe3+ ions,” J. Photochem. Photobiol. A Chem., vol. 435, p. 114284, Feb. 2023.
[14] X. Lin et al., “Carbon dots based on natural resources: Synthesis and applications in sensors,” Microchemical Journal, vol. 160, p. 105604, Jan. 2021.
[15] R. Atchudan et al., “Leftover Kiwi Fruit Peel-Derived Carbon Dots as a Highly Selective Fluorescent Sensor for Detection of Ferric Ion,” Chemosensors, vol. 9, no. 7, p. 166, Jul. 2021.
[16] S. Sahana, A. Gautam, R. Singh, and S. Chandel, “A recent update on development, synthesis methods, properties and application of natural products derived carbon dots,” Nat. Prod. Bioprospect., vol. 13, no. 1, p. 51, Dec. 2023.
[17] E. J. Rifna, N. N. Misra, and M. Dwivedi, “Recent advances in extraction technologies for recovery of bioactive compounds derived from fruit and vegetable waste peels: A review,” Crit. Rev. Food Sci. Nutr., vol. 63, no. 6, pp. 719–752, Feb. 2023.
[18] M. L. Desai, S. Jha, H. Basu, R. K. Singhal, T.-J. Park, and S. K. Kailasa, “Acid Oxidation of Muskmelon Fruit for the Fabrication of Carbon Dots with Specific Emission Colors for Recognition of Hg 2+ Ions and Cell Imaging,” ACS Omega, vol. 4, no. 21, pp. 19332–19340, Nov. 2019.
[19] C. N. Rahmi, S. Sugiarti, and A. D. Yuliani, “Karbon dots (C-dots) dari Bahan Hayati untuk Deteksi Logam Berat,” ALCHEMY Jurnal Penelitian Kimia, vol. 19, no. 2, p. 234, May 2023.
[20] A. Fadllan, P. Marwoto, M. P. Aji, Susanto, and R. S. Iswari, “Synthesis of carbon nanodots from waste paper with hydrothermal method,” 2017, p. 030069.
[21] V. Bressi, A. M. Balu, D. Iannazzo, and C. Espro, “Recent advances in the synthesis of carbon dots from renewable biomass by high-efficient hydrothermal and microwave green approaches,” Curr. Opin. Green Sustain. Chem., vol. 40, p. 100742, Apr. 2023.
[22] S. D. Torres Landa, N. K. Reddy Bogireddy, I. Kaur, V. Batra, and V. Agarwal, “Heavy metal ion detection using green precursor derived carbon dots,” iScience, vol. 25, no. 2, p. 103816, Feb. 2022.
[23] A. F. Fitri, R. F. Septiyanto, Y. R. D. Mukhtar, I. Affifah, I. Mustaqim, and W. P. K. Ayu, “APLIKASI CARBON DOTS MENGGUNAKAN LIMBAH KULIT SALAK DENGAN MENGGUNAKAN METODE MICROWAVE UNTUK PERTUMBUHAN TANAMAN CAISIM,” OPTIKA: Jurnal Pendidikan Fisika, vol. 9, no. 1, pp. 104–115, Jun. 2025.
[24] M. E. Raypah, M. F. Jamlos, H. S. Giwa, H. F. Ahmad, and H. A. Hamid, “Green synthesis of carbon dots derived from biomass of Polyalthia bullata root extract as colorimetric sensor for selective detection of Fe3+ ions,” Inorg. Chem. Commun., vol. 174, p. 113944, Apr. 2025.
[25] P. A. Putro and A. Maddu, “SIFAT OPTIK CARBON DOTS (C-DOTS) DARI DAUN BAMBU HASIL SINTESIS HIJAU BERBANTUKAN GELOMBANG MIKRO,” Wahana Fisika, vol. 4, no. 1, p. 47, Jun. 2019.
[26] X. Wen, J. Dong, R. Zhu, L. Shen, J. Fan, and X. Gao, “High-Yield Red Fluorescent Carbon Dots for Turn-On Detection of Fe3+ and Multicolor Cell Imaging,” 2025.
[27] S. Zhu, Y. Song, X. Zhao, J. Shao, J. Zhang, and B. Yang, “The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective,” Nano Res., vol. 8, no. 2, pp. 355–381, Feb. 2015.
[28] A. Başoğlu, Ü. Ocak, and A. Gümrükçüoğlu, “Synthesis of Microwave-Assisted Fluorescence Carbon Quantum Dots Using Roasted–Chickpeas and its Applications for Sensitive and Selective Detection of Fe3+ Ions,” J. Fluoresc., vol. 30, no. 3, pp. 515–526, May 2020.
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