SYNTHESIS OF MAGNETITE NANOPARTICLES (Fe3O4) BASED ON TAMAN RIVER SAND MAGNETIC MINERALS

Gusti Kade Agung Widiantara Agung; Ida Bagus Putu  Mardana; I Gede  Arjana

doi:10.29303/ipr.v7i3.314

SYNTHESIS OF MAGNETITE NANOPARTICLES (Fe3O4) BASED ON TAMAN RIVER SAND MAGNETIC MINERALS

Authors

Gusti Kade Agung Widiantara Agung , Ida Bagus Putu Mardana , I Gede Arjana

DOI:

10.29303/ipr.v7i3.314

Published:

2024-06-14

Issue:

Vol. 7 No. 3 (2024)

Keywords:

coprecipitation method, Fe3O4 characterization, nanoparticles, Synthesis

Articles

Downloads

PDF

How to Cite

Agung, G. K. A. W., Mardana, I. B. P. ., & Arjana, I. G. (2024). SYNTHESIS OF MAGNETITE NANOPARTICLES (Fe3O4) BASED ON TAMAN RIVER SAND MAGNETIC MINERALS. Indonesian Physical Review, 7(3), 327–337. https://doi.org/10.29303/ipr.v7i3.314

Abstract

This research aims to produce Fe3O4 magnetic nanoparticles-based Taman River sand as the raw material through coprecipitation. The Fe content percentage in the Taman River sand after separation was characterized using XRF testing. The lattice parameters and crystal size of the samples were tested using XRD. The nanoparticles' morphology, structure, particle shape, and elemental content were characterized using SEM-EDX. The magnetic properties and magnetic saturation values were tested using VSM. XRF testing results on the iron sand showed a Fe content of 84.72%. The synthesis resulted in a brNownish-black Fe3O4 nanoparticle powder that a permanent magnet could attract. Based on the XRD results, the Fe3O4 nanoparticle powder peaks were obtained at X-ray diffraction pattern angles of 2θ: 21.44°, 35.38°, 41.74°, 50.78°, 63.36°, 67.70°, and 74.66°, indicating the presence of Fe3O4 nanoparticles. The crystal structure formed was cubic with lattice parameters a = b = c = 8.331 Å and a crystal size of 18.43 nm. SEM-EDX results showed an average particle size of 25-30 nm. VSM results indicated that the Fe3O4 sample had a saturation magnetization (Ms) of 27.36 emu/g, a remanent magnetization (Mr) of -0.01 emu/g, and a coercive field (Hc) of 0.01 T.

References

M. D. Nguyen, H.-V. Tran, S. Xu, and T. R. Lee, "Fe3O4 Nanoparticles: Structures, Synthesis, Magnetic Properties, Surface Functionalization, and Emerging Applications," Applied Sciences, vol. 11, no. 23, p. 11301, Nov. 2021, doi: 10.3390/app112311301.

S. Bahtiar, F. Widyawati, E. Yanuar, R. Ramadhan, K. Zahra, and S. Hidayat, "Preparation of synthesis nanoparticles Fe3O4 based on iron sand Sumbawa," J. Pijar.MIPA, vol. 18, no. 6, pp. 959–963, Nov. 2023, doi: 10.29303/jpm.v18i6.5644.

K. Lee, and H. Kim, "Nanoparticles and Their Applications," Nanotechnology Reviews, vol. 10, no. 1, p. 45-58, 2021.

Y. Wang, and X. Li, "Magnetic Nanoparticles: Synthesis and Applications," International Journal of Nanomaterials, vol. 25, no. 2, p. 98-112, 2023

L. Zhao, and M. Chen, "Properties and Applications of Magnetite Nanoparticles," Materials Science Journal, vol. 16, no. 4, p. 210-225, 2020

A. Kumar, and P. Singh, "Magnetic Nanoparticles in Medical Applications," Journal of Biomedical Nanotechnology, vol. 14, no. 3, p. 78-92, 2022

R. Patel, and N. Shah, "Targeted Drug Delivery Using Fe3O4 Nanoparticles," Pharmaceutical Nanotechnology, vol. 19, no. 2, p. 130-145, 2021

S. Febriyani, and S. Syamsi, "Synthesis of Magnetite (Fe3O4) Nanoparticles from Iron Ore with the Addition of Lauric Acid," Jurnal Penelitian Bidang IPA dan Pendidikan IPA. vol. 9, no. 1, p. 57-69, Maret 2023.

R. Prasetyowati, D. Widiawati, P. E. Swastika, A. Ariswan, and W. Warsono, "Sintesis dan karakterisasi nanopartikel magnetite (Fe3O4) berbasis pasir besi Pantai Glagah Kulon Progo dengan metode kopresipitasi pada berbagai variasi konsentrasi NH4OH," JSD, vol. 10, no. 2, pp. 57–61, Nov. 2021, doi: 10.21831/jsd. v10i2.43043.

I.P. T. Indrayana, "Review Fe3O4 dari pasir besi: sintesis, karakterisasi, dan fungsionalisasi hingga aplikasinya dalam bidang nanoteknologi maju," Jurnal UNIERA, vol. 8, no. 2, p. 65-75, Aug. 2019.

I.O. Wulandari, L. B. Rahayu, I. Riva’I, H. Sulistyarti, and A. Sabarudin, "Sintesis dan Karakterisasi Nanopartikel Fe3O4 termodifikasi Biokompatibel Polimer serta Potensinya sebagai Penghantar Obat," The Indonesian Green Technology Journal. vol. 10, no. 1, p. 1-8, June 2021, doi: 10.21776/ub.igtj.2021.010.01.01.

B. A. Sadjab, I. P. T. Indrayana, S. Iwamony, and R. Umam, "Investigation of The Distribution and Fe Content of Iron Sand at Wari Ino Beach Tobelo Using Resistivity Method with Werner-Schlumberger Configuration," JIPFAlBiruni, vol. 9, no. 1, pp. 141–160, Apr. 2020, doi: 10.24042/jipfalbiruni.v9i1.5394.

T. Nguyen, and H. Vo, "Nanoparticles in Water Treatment," Journal of Environmental Nanotechnology, vol. 12, no. 2, p. 89-104, 2020.

R. Hernandez, and J. Lopez, "Synthesis and Characterization of Magnetic Nanoparticles for Electronic Applications," IEEE Transactions on Nanotechnology, vol. 17, no. 5, p. 333-345, 2021

N. Sirua, Suaedi, and A. Nurfalaq, "Karakterisasi kandungan mineral bijih besi (Fe) Sungai Maosu Desa Sangtandung Kecamatan Walenrang Kabupatem Luwu," Applied Physics of Cokroaminoto Palopo, vol. 3, no. 2, p. 48-52, 2022, doi: https://doi.org/10.30605/apcp.v3i2.148.

M. Sihombing and E. Amiruddin, "Sintesis dan Karakterisasi Nanopartikel Fe3O4 dari Pasir Alam Desa Logas Kabupaten Kuantan Singingi," JKFI, vol. 17, no. 2, p. 68, Jul. 2020, doi: 10.31258/jkfi.17.2.68-73.

V. A. Tiwow, M. Arsyad, P. Palloan, and M. J. Rampe, "Analysis of mineral content of iron sand deposit in Bontokanang Village and Tanjung Bayang Beach, South Sulawesi, Indonesia," J. Phys.: Conf. Ser., vol. 997, p. 012010, Mar. 2018, doi: 10.1088/1742-6596/997/1/012010.

A. C. B. Jesus et al., "Synthesis and magnetic interaction on concentrated Fe3O4 nanoparticles obtained by the co-precipitation and hydrothermal chemical methods," Ceramics International, vol. 46, no. 8, pp. 11149–11153, Jun. 2020, doi: 10.1016/j.ceramint.2020.01.135

P. E. Swastika, F. Hardheyanti, R. Prasetyowati, A. Ariswan, and W. Warsono, "Pengaruh Konsentrasi HCl terhadap Mikrostruktur dan Sifat Kemagnetan Nanopartikel Fe3O4 yang Disintesis dari Pasir Besi Pantai Glagah Kulonprogo," JSD, vol. 10, no. 1, pp. 24–29, May 2021, doi: 10.21831/jsd.v10i1.39141.

N. Bukit, E. Frida, P. Simamora, and T. Sinaga, "Analisis Difraksi Nanopartikel Fe3O4 Metode Kopresipitasi Dengan Polietilen Glikol 6000," Prosiding Seminar Nasional Fisika (E-Journal), vol. 4, Oct. 2015. [Online]. Available: http://snf-unj.ac.id/kumpulan-prosiding/snf2015/. [Accessed Mey. 27, 2024

Z. Raji, A. Karim, A. Karam, and S. Khalloufi, "Adsorption of Heavy Metals: Mechanisms, Kinetics, and Applications of Various Adsorbents in Wastewater Remediation—A Review," Waste, vol. 1, no. 3, pp. 775–805, Sep. 2023, doi: 10.3390/waste1030046.

Z. Li, J. Wei, J. Liu, & H. Li, "Applications of magnetic nanoparticles in environmental remediation: a review," Chemical Engineering Journal, vol. 300, p. 155-164, 2016

M. Mahmoudi, S. Sant, B. Wang, S. Laurent, and T. Sen, "Superparamagnetic iron oxide nanoparticles (SPIONs): Development, surface modification and applications in chemotherapy," Advanced Drug Delivery Reviews, vol. 63, no. 1–2, pp. 24–46, Jan. 2011, doi: 10.1016/j.addr.2010.05.006.

G. Subhashini, P. Ruban, and T. Daniel, "Biosynthesis and characterization of Magnetic (Fe3O4) Iron oxide nanoparticles from a red seaweed gracilaria edulis and its antimicrobial activity,” International Journal of Advanced Scientific Research and Management, vol. 3, no 10, p. 184-189, Oct. 2018

K. Kurnia, M. Kaseside, and S. Iwamony, "Study Microstructure of Fe3O4 Modification Using PEG 4000 form Iron Sand at Wari Ino Beach As A Biosensor Application," Indo. J. Chem. Res., vol. 8, no. 3, pp. 168–171, Jan. 2021, doi: 10.30598//ijcr.2021.8-kur.

M. Rianna et al., "Study and characterization of Fe3O4 synthesized from natural iron sand in Sumatera Utara," J. Aceh Phys. Soc., vol. 11, no. 2, pp. 45–48, Apr. 2022, doi: 10.24815/jacps.v11i2.23492.

F. Chen, N. Ilyas, X. Liu, Z. Li, S. Yan, and H. Fu, "Size Effect of Fe3O4 Nanoparticles on Magnetism and Dispersion Stability of Magnetic Nanofluid," Front. Energy Res., vol. 9, p. 780008, Nov. 2021, doi: 10.3389/fenrg.2021.780008.

T. Saragi, U. Widyaiswari, D. J. Manalu, B. Adiperdana, R. Risdiana, and T. Adachi, "Particle size and its distribution deduced from magnetic properties of magnetite nanoparticles by the modified Langevin equation," AIP Advances, vol. 13, no. 9, p. 095103, Sep. 2023, doi: 10.1063/5.0167090.

J. M. D. Coey, " Applications of Soft Magnets," in Magnetism and Magnetic Materials. New York, U.S. Cambridge University Press, 2010, ch. 12, pp. 439-457.

License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Authors who publish with Indonesian Physical Review Journal, agree to the following terms:

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-ShareAlike 4.0 International Licence (CC BY SA-4.0). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Indonesian Physical Review Journal.
Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).

SYNTHESIS OF MAGNETITE NANOPARTICLES (Fe3O4) BASED ON TAMAN RIVER SAND MAGNETIC MINERALS

Authors

DOI:

Published:

Issue:

Keywords:

Articles

Downloads

How to Cite

Abstract

References

License

Official Website Of

Indonesian Physical Review, University of Mataram

Contact Us

Official link

Share & Follow