SYNTHESIS AND CHARACTERIZATION OF CaO PREPARED FROM LIMESTONE USING SOL-GEL METHOD

Fatimatul Munawaroh; Yoga Masdya; Malik Anjelh Baqiya; Triwikantoro Triwikantoro

doi:10.29303/ipr.v7i2.313

SYNTHESIS AND CHARACTERIZATION OF CaO PREPARED FROM LIMESTONE USING SOL-GEL METHOD

Authors

Fatimatul Munawaroh , Yoga Masdya , Malik Anjelh Baqiya , Triwikantoro Triwikantoro

DOI:

10.29303/ipr.v7i2.313

Published:

2024-04-29

Issue:

Vol. 7 No. 2 (2024)

Keywords:

CaO, sol-gel, XRD, CO2 Capture

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Munawaroh, F., Masdya, Y., Baqiya, M. A., & Triwikantoro, T. (2024). SYNTHESIS AND CHARACTERIZATION OF CaO PREPARED FROM LIMESTONE USING SOL-GEL METHOD. Indonesian Physical Review, 7(2), 249–258. https://doi.org/10.29303/ipr.v7i2.313

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Abstract

The sol-gel method has been successfully applied to the synthesis and characterization of calcium oxide (CaO) derived from calcite-based natural limestone from Pamekasan, Madura, East Java Indonesia. Controlled dissolution, titration, gel formation, and subsequent calcination at temperatures 650°C and 900°C were the steps involved in the synthesis. X-ray diffraction was used for characterization to identify the phase that had formed. Supporting software, MATCH! used to analyze the phases and structures and Rietica for refinement using the Rietveld method. The Ca(OH)2 phase formed was 59.65 ± 2.45 %wt before the calcination process, according to the XRD results. 23.71 ± 0.61 %wt CaO was produced by the calcination process at 650°C, and 64.52 ± 1.85 %wt was produced at 900°C. Meanwhile, after calcination at 900°C, crystal size analysis using MAUD software produced CaO with a size of 534 ± 74 nm. K CaO powder synthesized using the sol-gel method is calcined at 900°C to get a higher percentage than at 600°C. The CaO powder can be used for CO2 capture applications because it comes from natural resources and is environmentally friendly.

References

Z. Mirghiasi, F. Bakhtiari, E. Darezereshki, and E. Esmaeilzadeh, “Preparation and characterization of CaO nanoparticles from Ca(OH)2 by direct thermal decomposition method,” J. Ind. Eng. Chem., vol. 20, no. 1, pp. 113–117, 2014, doi: 10.1016/j.jiec.2013.04.018.

E. E. Khine et al., “Synthesis and characterization of calcium oxide nanoparticles for CO2 capture,” J. Nanoparticle Res., vol. 24, no. 7, 2022, doi: 10.1007/s11051-022-05518-z.

Y. Q. Geng, Y. X. Guo, B. Fan, F. Q. Cheng, and H. G. Cheng, “Research progress of calcium-based adsorbents for CO2 capture and anti-sintering modification,” Ranliao Huaxue Xuebao/Journal Fuel Chem. Technol., vol. 49, no. 7, pp. 998–1013, 2021, doi: 10.1016/S1872-5813(21)60040-3.

H. Guo, S. Wang, C. Li, Y. Zhao, Q. Sun, and X. Ma, “Incorporation of Zr into Calcium Oxide for CO2 Capture by a Simple and Facile Sol-gel Method Incorporation of Zr into Calcium Oxide for CO 2 Capture by a Simple and Facile Sol-gel Method,” 2016, doi: 10.1021/acs.iecr.5b04112.

M. Broda and C. R. Müller, “Sol-gel-derived, CaO-based, ZrO2-stabilized CO2 sorbents,” Fuel, vol. 127, pp. 94–100, 2014, doi: 10.1016/j.fuel.2013.08.004.

A. Scaltsoyiannes, A. Antzaras, G. Koilaridis, and A. Lemonidou, “Towards a generalized carbonation kinetic model for CaO-based materials using a modified random pore model,” Chem. Eng. J., vol. 407, p. 127207, 2021, doi: 10.1016/j.cej.2020.127207.

A. M. Kierzkowska, R. Pacciani, and C. R. Müller, “CaO-based CO2 sorbents: From fundamentals to the development of new, highly effective materials,” ChemSusChem, vol. 6, no. 7, pp. 1130–1148, 2013, doi: 10.1002/cssc.201300178.

S. A. Salaudeen, B. Acharya, and A. Dutta, “CaO-based CO2 sorbents: A review on screening, enhancement, cyclic stability, regeneration and kinetics modelling,” J. CO2 Util., vol. 23, no. July 2017, pp. 179–199, 2018, doi: 10.1016/j.jcou.2017.11.012.

G. S. Grasa and J. C. Abanades, “CO2 capture capacity of CaO in long series of carbonation/calcination cycles,” Ind. Eng. Chem. Res., vol. 45, no. 26, pp. 8846–8851, 2006, doi: 10.1021/ie0606946.

F. Munawaroh, L. Khamsatul Muharrami, T. Triwikantoro, and Z. Arifin, “Calcium Oxide Characteristics Prepared From Ambunten’s Calcined Limestone,” J. Pena Sains, vol. 5, no. 1, 2018.

A. Lesbani, S. O. Ceria Sitompul, R. Mohadi, and N. Hidayati, “Characterization and Utilization of Calcium Oxide (CaO) Thermally Decomposed from Fish Bones as a Catalyst in the Production of Biodiesel from Waste Cooking Oil,” Makara J. Technol., vol. 20, no. 3, p. 121, 2016, doi: 10.7454/mst.v20i3.3066.

C.- Pujiastuti, S. Muljani, and K. Sumada, “Precipitated calcium oxide nanosize from limestone and blood clam shells,” J. Nat. Sci. Math. Res., vol. 9, no. 1, pp. 12–18, 2023, doi: 10.21580/jnsmr.2023.9.1.13209.

F. Granados-Correa and M. Jiménez-Reyes, “Evaluation of CO2adsorption capacity with a nano-CaO synthesized by chemical combustion/ball milling,” Mater. Sci. Pol., vol. 40, no. 2, pp. 257–269, 2022, doi: 10.2478/msp-2022-0024.

H. Sun, C. Wu, B. Shen, X. Zhang, Y. Zhang, and J. Huang, “Progress in the development and application of CaO-based adsorbents for CO2 capture—a review,” Mater. Today Sustain., vol. 1–2, pp. 1–27, 2018, doi: 10.1016/j.mtsust.2018.08.001.

M. Broda, A. M. Kierzkowska, and C. R. Müller, “Application of the Sol – Gel Technique to Develop Synthetic Calcium-Based Sorbents with Excellent Carbon Dioxide Capture Characteristics,” pp. 411–418, 2012, doi: 10.1002/cssc.201100468.

R. G. Jalu, T. A. Chamada, and R. Kasirajan, “Calcium oxide nanoparticles synthesis from hen eggshells for removal of lead ( Pb ( II )) from aqueous solution,” Environ. Challenges, vol. 4, no. February, p. 100193, 2021, doi: 10.1016/j.envc.2021.100193.

H. R. Radfarnia and A. Sayari, “A highly efficient CaO-based CO2 sorbent prepared by a citrate-assisted sol-gel technique,” Chem. Eng. J., vol. 262, pp. 913–920, 2015, doi: 10.1016/j.cej.2014.09.074.

G. K. Reddy, S. Quillin, and P. Smirniotis, “Influence of the synthesis method on the structure and CO2 adsorption properties of Ca/Zr sorbents,” Energy and Fuels, vol. 28, no. 5, pp. 3292–3299, 2014, doi: 10.1021/ef402573u.

K. S. Sultana, D. T. Tran, J. C. Walmsley, M. Rønning, and D. Chen, “CaO Nanoparticles Coated by ZrO2 Layers for Enhanced CO2 Capture Stability,” Ind. Eng. Chem. Res., vol. 54, no. 36, pp. 8929–8939, 2015, doi: 10.1021/acs.iecr.5b00423.

Y. Hu, H. Lu, W. Liu, Y. Yang, and H. Li, “Incorporation of CaO into inert supports for enhanced CO2 capture: A review,” Chem. Eng. J., vol. 396, no. February, p. 125253, 2020, doi: 10.1016/j.cej.2020.125253.

L. Habte, N. Shiferaw, D. Mulatu, T. Thenepalli, R. Chilakala, and J. W. Ahn, “Synthesis of nano-calcium oxide fromwaste eggshell by sol-gel method,” Sustain., vol. 11, no. 11, pp. 1–10, 2019, doi: 10.3390/su11113196.

F. Munawaroh, L. K. Muharrami, T. Triwikantoro, and Z. Arifin, “Characterization of Limestone in Pamekasan Madura Island as Raw Material for Producing Nano Precipitated Calcium Carbonate (NPCC),” 2018, doi: 10.1088/1757-899X/395/1/012009.

L. Lutterotti, “MAUD - Materials Analysis Using Diffraction (and more),” 2024. https://luttero.github.io/maud/ (accessed Jan. 22, 2024).

N. Widiarti et al., “CATALYTIC ACTIVITY OF CALCIUM OXIDE FROM FISHBONE WASTE IN WASTE COOKING OIL TRANSESTERIFICATION PROCESS,” J. Bahan Alam Terbarukan, vol. 6, no. 2, pp. 97–106, 2017, doi: 10.15294/jbat.v6i2.8335.

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SYNTHESIS AND CHARACTERIZATION OF CaO PREPARED FROM LIMESTONE USING SOL-GEL METHOD

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