Vol. 8 No. 1 (2025)
Open Access
Peer Reviewed

THE EFFECT OF CALCINATION TEMPERATURE AND HOLDING TIME ON STRUCTURAL PROPERTIES OF CALCIA POWDERS DERIVED FROM EGGSHELL WASTE

Authors

Budi Prayitno , Musyarofah Musyarofah , Gusti Umindya Nur Tajalla , Azmia Rizka Nafisah , Siti Norhidayah , Siska Ayu Kartika

DOI:

10.29303/ipr.v8i1.450

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Received: Dec 18, 2024
Accepted: Jan 21, 2025
Published: Jan 22, 2025

Abstract

This study investigates the effects of calcination temperature and holding time on the structural properties of calcia (CaO) powders. The raw material used in this study is chicken eggshell waste, which was cleaned, dried, ground, and sieved for uniform particle size. The synthesis of calcia powder was performed by calcining the powder at 900°C and 1000 °C for 5, 10, and 15 hours. XRD, BET, and SEM analyses were employed to evaluate crystal structure, textural properties, and microstructure of the calcined powders. The Rietveld analysis reveals the identified crystalline phases were calcia up to 95.6 mol% and calcium hydroxide as secondary phase. Results indicate that higher calcination temperatures and extended holding times increase particle size and reduce BET surface area, significantly altering pore size distribution. Specifically, elevated temperatures promote sintering and grain growth, leading to smaller average pore radii and decreased total pore volume. The BET surface area ranges from 7.431 m2/g to 1.772 m2/g for samples calcined at 900 °C and from 3.202 m²/g to 0.711 m²/g for samples calcined at 1000 °C. Correspondingly, the average particle radius increases from 183.51 nm to 769.55 nm at 900 °C and from 425.83 nm to 1918.10 nm at 1000 °C as the holding time extends. BJH analysis reveals that longer holding times broaden pore size distribution due to the merging of smaller pores.

Keywords:

Calcia, Calcination, Holding time, Microstructure, Structure, Temperature

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Author Biographies

Budi Prayitno, Department of Mechanical Engineering, Universitas Balikpapan, Jln. Pupuk Raya, Balikpapan 76114, Indonesia

Musyarofah Musyarofah, Department of Physics, Institut Teknologi Kalimantan

Gusti Umindya Nur Tajalla, Department of Materials and Metallurgical Engineering, Institut Teknologi Kalimantan

Azmia Rizka Nafisah, Department of Chemical Engineering, Institut Teknologi Kalimantan

Siti Norhidayah, Department of Mechanical Engineering, Universitas Balikpapan

Siska Ayu Kartika, Department of Mechanical Engineering, Universitas Balikpapan

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How to Cite

Prayitno, B., Musyarofah, M., Tajalla, G. U. N., Nafisah, A. R., Norhidayah, S., & Kartika, S. A. (2025). THE EFFECT OF CALCINATION TEMPERATURE AND HOLDING TIME ON STRUCTURAL PROPERTIES OF CALCIA POWDERS DERIVED FROM EGGSHELL WASTE. Indonesian Physical Review, 8(1), 281–299. https://doi.org/10.29303/ipr.v8i1.450

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